A lot of us do this all the time Ace, we call it drills. If you wait until a true emergency, then you will have to waste a bit of time to think prior to reacting; if you practice these skills on a regular basis, it becomes second nature (muscle memory and all that garbage.) Even when I am diving solo, I will breathe my backup from time to time just to ensure its functionality.
As for banging the NDL's with an AL 80, it can be done quite easily. This is especially true for more experienced divers (the more you dive the more relaxed you should become and thus the better your SAC rate.) Women are notorius for having extremely low SAC rates to begin with, but I have met my share of male divers who I swear had to have gill implants.